http://www.startuk.org/food/seed-bombs.aspx Above a link to a site explaining how to make seed bombs. Sorry, you'll have to paste and copy link into your browser rather than click on it directly. Basically it's seed mixed into a ball of mud, which can then be pushed into wall crevices. You could try this, or sow seed into modules and then push into crevices when well rooted. I have miles of toadflax on my Walls, no idea where it came from - but I yank it out periodically. Slugs and snails love sheltering behind it - be warned! And I wouldn't let valerian take hold either, the roots get enormous and could bring the whole wall down. You might also think of wallflowers - might sound a bit corny, but they can be kept going for years if you cut back after flowering.