Definitely caper spurge - if you're going to pull them up wear gloves and long sleeves - if you get the sap on your skin, especially on a sunny day, you'll get huge painful red wheals across your skin - I was quite poorly when as a child I decided to clear an overgrown part of the garden on a very sunny day.
On the plus side - they're supposed to deter moles. No idea if there's any evidence for it.