All these weed killers kill weeds, something stronger wouldn't make them any more dead. Pathclear makes a layer on top of the soil (in theory) this stops more coming through. If the seeds are being blown on top of that it won't work and a good strong weed will be able to pentrate through to the soil beneath.
My solution (if I could afford the time and money) would be between concrete, block paving and tarmac.